Reservoir Engineering Strong Magnomechanical Entanglement via Dual-Mode Cooling

A hybrid cavity magnomechanical system to transfer the bipartite entanglements and achieve the strong microwave photon–phonon entanglement based on the reservoir engineering approach is constructed. The magnon mode is coupled to the microwave cavity mode via magnetic dipole interaction and to the phonon mode via magnetostrictive force (optomechanical-like). It is shown that the initial magnon-phonon entanglement can be transferred to the photon-phonon subspace in the case of these two interactions cooperating. In the reservoir-engineering parameter regime, the initial entanglement is directionally transferred to the photon-phonon subsystem, so a strong bipartite entanglement in which the magnon mode acts as the cold reservoir to effectively cool the Bogoliubov mode delocalized over the cavity and the mechanical deformation mode is obtained. Moreover, dual-mode cooling is realized by engineering the dissipation of photon and phonon modes within the target mode, which allows entanglement to be further enhanced. The results indicate that the steady-state entanglement is robust against temperature. The dual-mode cooling reservoir engineering scheme can potentially be extended to other three-mode quantum systems.     

二甲双胍化学反应性的密度泛函理论研究及实验研究

二甲双胍(MET)是一个非常优良的降血糖药,一直是治疗II型糖尿病(T2DM)的首选药物,但其脂溶性较差,也存在引起胃肠道不适等副作用,对其结构修饰和衍生化,特别是将其研制成前药(Prodrug)具有一定的临床意义。为了探明二甲双胍化学反应的性能特点,本文基于密度泛函理论（DFT）开展了二甲双胍的化学内禀性质研究,包括各种可能互变异构体的单点能和量子化学反应性指数。此外,还对各异构体互变过程的过渡态以及它们的反应路径进行了研究。在此基础上,本文还对二甲双胍与亲电试剂的化学反应机理进行了初探,并用化学合成反应来验证,从而让我们能够从理论上弄清楚二甲双胍化学反应的特殊性质。     

Acetylene Derivatives of Cationic Diazaoxatriangulenes and Diaza [4]Helicenes - Access to Red Emitters and Planar Chiral Stereochemical Traits

Cationic triangulenes, and related helicenes, constitute a rich class of dyes and fluorophores, usually absorbing and emitting light at low energy, in the orange to red domains. Recently, to broaden the scope of applications, regioselective late-stage functionalizations on these core moieties have been developed. For instance, with the introduction of electron-donating groups (EDGs), important bathochromic shifts are observed pushing absorptions towards or in the near-infrared (NIR) spectral domain while emissive properties disappear essentially completely. Herein, to upset this drawback, acetylene derivatives of cationic diazaoxa triangulenes (DAOTA) and [4]helicenes are prepared (16 examples). Contrary to other EDG-functionalized derivatives, C≡C− functionalized products remain broadly fluorescent, with red-shifted absorptions (Δλ_abs up to 25 nm) and emissions (Δλ_em up to 73 nm, Φ_PL up to 51 %). Quite interestingly, a general dynamic stereoisomerism phenomenon is evidenced for the compounds derived from achiral DAOTA cores. At low temperature in ¹H NMR spectroscopy (218 K), N−CH₂ protons become diastereotopic with chemical shifts differences (Δδ) as high as +1.64 ppm. The signal coalescence occurs around 273 K with a barrier of ∼12 kcal mol⁻¹. This phenomenon is due to planar chiral conformations (S_p and R_p configurations), induced by the geometry of the alkyl (n-propyl) side-chains next to the acetylenic substituents. Ion pairing studies with Δ-TRISPHAT anion not only confirm the occurrence of the chiral conformations but evidence a moderate but definite asymmetric induction from the chiral anion onto the cations. Finally, DFT calculations offer a valuable insight on the geometries, the corresponding stereodynamics and also on the very large difference in NMR for some of the diastereotopic protons.     

能源与环境应用中的微波催化研究进展

微波是一种能量传递方式。与传统电加热相比,微波加热具有加热速度快、热惯性小、选择性加热等特点,因而被视为一种优质的能量来源。微波催化是一种使用微波对反应系统供能,从而推动催化反应进行的化学过程。近年来,许多研究者致力于探索和发展微波催化技术,包括利用微波技术提升化学反应速率、开发具有出色微波吸收能力的催化剂、建立节能环保的微波催化系统等。本文首先介绍了微波的相关理论,讲述了材料对微波的吸收原理;然后从微波催化降解挥发性有机物（Volatile Organic Compounds, VOCs）、微波催化污水处理、微波催化生物质热解和微波催化碳氢化合物转化等方面综述了微波催化在能源环境中的应用;最后对微波催化过程的机理展开了讨论。     

Shear-opposed mixed-convection flow and heat transfer in a narrow, vertical cavity

A combined experimental and theoretical study has been carried out to investigate mixed-convection heat transfer in a narrow, vertical cavity. The shear force is produced at the left side of a cavity by a belt moving upward that constitutes the sixth wall of the cavity. The left wall of the cavity was cooled and the opposite (right wall) was heated. Hence, the buoyancy force tries to bring the fluid down, and the shear force tends to induce upward fluid flow. The test cell was equipped with two heat exchangers and three thermocouple racks for measuring the temperature distributions at 12 different positions. The temperature field was scanned in the cavity for various flow and temperature boundary conditions. Three-and-two-dimensional laminar models were used to analyze the problem theoretically. The experimental measurements were found to be in good agreement with the numerical predictions.     

Analytical Solutions to Expansion of Cylindrical Cavity in Linear Softening Soil

Based on the results of conventional triaxial compression tests for a soil, a trilinear elasto-plastic model is proposed to simulate the stress-strain softening curve. According to this curve, the constitutive relation between the bulk strain and two pr…     

浅埋的圆柱形孔洞对SH波的散射与地震动

研究了浅埋的圆柱形孔洞对以任意方向入射的平面SH波的散射与地震动问题。利用复变函数和多极坐标方法构造了问题的位移解。当入射波的波长与圆孔的半径相比较小时,地震动将受到较大的影响。影响地震动有三个主要参数:(1)SH波的入射角0;(2)入射波波数,即圆柱形孔洞的半径与入射波半波长之比;(3)h/R,即圆柱形孔洞至表面的距离与圆孔半径之比。当较大时,地震动幅值变化激烈,位移幅值可出现跳动和放大的现象。当h/R增大至10～12时,位移幅值变化恢复至半空间的情况,表明圆柱形孔洞的影响可被忽略。     

通气法控制超空泡流动的实验研究

在高速水洞中运用人工通气方法进行了航行体模型超空泡形态特性的系列实验研究.获得了不同通气流量、不同空化数和不同弗鲁德数下的空泡形态,建立了以弗鲁德数为参数的空泡几何特征参数与空化数的对应关系、空化数与通气流量系数之间的对应关系.验证了空化数是决定空泡尺度的主要无因次参数,通过改变通气流量可以有效地调控空化数,进而达到控制空泡形态的目的.文中同时给出了通气流量系数的实验曲线拟合公式,并与国外的相关实验和公式进行了比较,两者基本一致.所得结论对进一步的水下超高速航行体空泡形态控制技术研究具有参考价值.     

Sustained photon pulse revivals from inhomogeneously broadened spin ensembles

A very promising recent trend in applied quantum physics is to combine the advantageous features of different quantum systems into what is called “hybrid quantum technology”. One of the key elements in this new field will have to be a quantum memory enabling to store quanta over extended periods of time. Systems that may fulfill the demands of such applications are comb‐shaped spin ensembles coupled to a cavity. Due to the decoherence induced by the inhomogeneous ensemble broadening, the storage time of these quantum memories is, however, still rather limited. Here we demonstrate how to overcome this problem by burning well‐placed holes into the spectral spin density leading to spectacular performance in the multimode regime. Specifically, we show how an initial excitation of the ensemble leads to the emission of more than a hundred well‐separated photon pulses with a decay rate significantly below the fundamental limit of the recently proposed “cavity protection effect”.

     

Dynamic stress of a circular cavity buried in a semi-infinite functionally graded piezoelectric material subjected to shear waves

The paper presents a theoretical method to investigate the multiple scattering of shear waves and dynamic stress around a circular cavity in a semi-infinite functionally graded piezoelectric material. The analytical solutions of wave fields are expressed by employing wave function expansion method and the expanded mode coefficients are determined by satisfying the boundary conditions of the cavity. Image method is used to satisfy the free boundary condition of the semi-infinite structure. According to the analytical expression of this problem, the numerical solutions of the dynamic stress concentration factor around the cavity are presented. The effects of the piezoelectric property, the buried depth of the cavity, the incident wave number and the nonhomogeneous parameter of materials on the dynamic stress around the cavity are analyzed. Analyses show that the piezoelectric property has great effect on the dynamic stress in the region of intermediate frequency and the effect increases with increasing wave number. When the nonhomogeneous parameter of materials is less than zero, it has less influence on the maximum dynamic stress around the cavity; however, it has greater influence on the distribution of the dynamic stress around the cavity. When the nonhomogeneous parameter of materials is greater than zero, it has greater influence on both the maximum dynamic stress and the distribution of dynamic stress around the cavity, especially in the case that the buried depth is comparatively small.